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On the addition of chlorine to tropilidene

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Conclusions

  1. 1.

    Tropilidene easily adds six atoms of chlorine forming a complex mixture of stereoisomeric 1,2,3,4,5,6-hexachlorocycloheptanes.

  2. 2.

    The stereoisomers described can be separated by frontal chromatography on aluminum oxide.

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Literature cited

  1. 1.

    G. Merling, Ber.,24, 3108 (1891).

  2. 2.

    W. von E. Doering and L. H. Knox, J. Amer. Chem. Soc.,76, 3203 (1954).

  3. 3.

    M. A. Pryanishnikova, E. M. Mil'vitskaya, and A. F. Platé, Izv. AN SSSR, Otd. khim. n.,1960, 2178.

  4. 4.

    M. A. Pryanishnikova, G. V. Golovkin, A. F. Plate, N. F. Kononov, and V. V. Zarutskii, Izv. AN SSSR, Ser. khim.,1967, 1127.

  5. 5.

    M. A. Pryanishnikova, G. M. Dugacheva, A. F. Platé, and A. G. Anikin, Dokl. AN SSSR,132, 857 (1960).

  6. 6.

    M. Busch and H. Stöve, Ber.,49, 1063 (1916).

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2093–2095, September, 1967.

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Liberman, A.L., Pryanishnikova, M.A. & Golovkin, G.V. On the addition of chlorine to tropilidene. Russ Chem Bull 16, 2014–2016 (1967). https://doi.org/10.1007/BF00909608

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Keywords

  • Oxide
  • Aluminum
  • Chromatography
  • Chlorine
  • Complex Mixture