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On the addition of chlorine to tropilidene

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  1. 1.

    Tropilidene easily adds six atoms of chlorine forming a complex mixture of stereoisomeric 1,2,3,4,5,6-hexachlorocycloheptanes.

  2. 2.

    The stereoisomers described can be separated by frontal chromatography on aluminum oxide.

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Literature cited

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    M. A. Pryanishnikova, E. M. Mil'vitskaya, and A. F. Platé, Izv. AN SSSR, Otd. khim. n.,1960, 2178.

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    M. A. Pryanishnikova, G. V. Golovkin, A. F. Plate, N. F. Kononov, and V. V. Zarutskii, Izv. AN SSSR, Ser. khim.,1967, 1127.

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    M. A. Pryanishnikova, G. M. Dugacheva, A. F. Platé, and A. G. Anikin, Dokl. AN SSSR,132, 857 (1960).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2093–2095, September, 1967.

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Liberman, A.L., Pryanishnikova, M.A. & Golovkin, G.V. On the addition of chlorine to tropilidene. Russ Chem Bull 16, 2014–2016 (1967). https://doi.org/10.1007/BF00909608

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  • Oxide
  • Aluminum
  • Chromatography
  • Chlorine
  • Complex Mixture