The infrared absorption spectra of 1-nitro-1-propylene,Β -nitrostyrene,Β -nitroacrylic acid, and its methyl ester confirm the trans-structure of the 1,2-disubstituted nitroolefins RCH=CHNO2.
On irradiation by ultraviolet light the trans-nitroolefins RCH=CHNO2 isomerize into the corresponding cis-nitroolefins.
In the case ofΒ -nitrostyrene and cyclopentadiene it has been shown that the spacial arrangement of the substituents in the nitroolefins RCH=CHNO2 has a considerable effect on the occurrence of the diene syntheis
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E. E. Tamelen and R. J. Thiede, J. Amer. Chem. Soc.74, 2615 (1952).
L. Bellamy, Infrared Spectra of Molecules [Russian translation] IL, Moscow, 1957, p. 54.
N. Potts and R. Nyguist, Spectrochim. acta, No. 9, 679 (1959).
N. Sheppard and D. Simpson, Quart. Revs. 6, 1 (1952).
N. K. Kochetkov, B. P. Gottikh, V. G. Vinokurov, and R. M. Khomutov, Doklady Akad. Nauk SSSR125, 89 (1959).
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Dudunskaya, A.A., Shvekhgeimer, G.A., Novikov, S.S. et al. The effect of configuration of nitrodienophiles R-CH=CH-NO2 on their condensation with cyclopentadiene. Russ Chem Bull 10, 168–170 (1961). https://doi.org/10.1007/BF00909434
- Absorption Spectrum
- Methyl Ester