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Dehydration of n-alkanes on the catalyst K-5

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Summary

  1. 1.

    The dehydrogenation of n-alkanes of composition C5-C10, and also n-hexadecane and cyclohexane on the catalystK 5 at 500° with a volume rate of 2.1 hr−1 has been studied.

  2. 2.

    The n-alkane catalyzates obtained under these conditions contained 8–12% of the corresponding alkenes. n-Hexadecane underwent considerable cracking.

  3. 3.

    The catalyst possesses weak aromatizing and isomerizing power.

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Literature cited

  1. 1.

    E. A. Timofeeva, N. I. Shuikin, Yu. N. Plotnikov, and V. M. Kleimenova, Dokl. AN SSSR,125, 1275 (1959).

  2. 2.

    E. A. Timofeeva, N. I. Shuikin, Yu. N. Plotnikov, and V. M. Kleimenova, Dokl. AN SSSR,129, 128 (1959).

  3. 3.

    E. A. Timofeeva, V. S. Smirnov, and V. I. Zaeva, Kinetika i Kataliz,1, No. 2, 1300 (1960).

  4. 4.

    R. D. Obolentsev, Physical Constants of the Hydrocarbons of Liquid Oils [in Russian] (Gostoptekhizdat, Moscow, 1953).

  5. 5.

    E. A. Timofeeva, N. I. Shuikin, T. P. Dobrynina, G. S. Petryaeva, and Yu. N. Plotnikov, Izv. AN SSSR, Otd. Khim. N. 292 (1960).

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Shuikin, N.I., Timofeeva, E.A. & Kleimenova, V.M. Dehydration of n-alkanes on the catalyst K-5. Russ Chem Bull 10, 603–606 (1961). https://doi.org/10.1007/BF00909129

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Keywords

  • Dehydration
  • Alkene
  • Cyclohexane
  • Dehydrogenation
  • Volume Rate