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Iron carbonyls as inhibitors of thiol addition to phenylacetylene and cis-trans isomerization of vinyl sulfides

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Conclusions

  1. 1.

    Fe(CO)5 and [Fe(CO)3SC2H5]2 are effective inhibitors of radical isomerization of vinyl sulfides.

  2. 2.

    Fe(CO)5 and [Fe(CO)3SC2H5]2 inhibit the radical addition of thiols to phenylacetylene.

  3. 3.

    Mo(CO)6 and W(CO)6 display only a weak decelerating effect on the indicated reactions.

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Literature cited

  1. 1.

    R. G. Petrova, I. I. Kandror, and R. Kh. Freidlina, Zh. Organ. Khim.,3, 1942 (1967).

  2. 2.

    I. I. Kandror, R. G. Petrova, and R. Kh. Freidlina, Izv, Akad. Nauk SSSR, Ser. Khim., 1373 (1968).

  3. 3.

    A. A. Oswald, K. Griesbaum, B. E. Hudson, Jr., and J. M. Bregman, J. Amer. Chem. Soc.,86, 2877 (1964).

  4. 4.

    T. A. Manuel, Advances in Organometal. Chem.,3, 181 (1965).

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    W. E. Truce and J. A. Simms, J. Amer. Chem. Soc.,78, 2756 (1956).

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1621–1624, July, 1969.

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Kandror, I.I., Petrova, R., Petrovskii, P.V. et al. Iron carbonyls as inhibitors of thiol addition to phenylacetylene and cis-trans isomerization of vinyl sulfides. Russ Chem Bull 18, 1508–1510 (1969). https://doi.org/10.1007/BF00908767

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Keywords

  • Iron
  • Sulfide
  • Carbonyl
  • Vinyl
  • Thiol