Fe(CO)5 and [Fe(CO)3SC2H5]2 are effective inhibitors of radical isomerization of vinyl sulfides.
Fe(CO)5 and [Fe(CO)3SC2H5]2 inhibit the radical addition of thiols to phenylacetylene.
Mo(CO)6 and W(CO)6 display only a weak decelerating effect on the indicated reactions.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1621–1624, July, 1969.
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Kandror, I.I., Petrova, R., Petrovskii, P.V. et al. Iron carbonyls as inhibitors of thiol addition to phenylacetylene and cis-trans isomerization of vinyl sulfides. Russ Chem Bull 18, 1508–1510 (1969). https://doi.org/10.1007/BF00908767