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The O-nitration of tertiary unsaturated alcohols andα-epoxyalcohols

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Conclusions

The method for O-nitrating unsaturated alcohols andα-epoxyalcohols has been extended to tertiary alcohols;α, α-dimethylallyl andα, α;-dimethylglycidyl nitrates have been synthesized.

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Literature cited

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    L. T. Eremenko and A. M. Korolev, Izv. AN SSSR, Ser. khim.,1966, 1426.

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    M. L. Wolfrom, G. H. McFadden, and A. Chaney, J. Organ. Chem.,25, 1079 (1960).

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    I. N. Nazarov and I. N. Azarbaev, Zh. obshch. khimii,18, 414 (1948).

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    G. B. Payne, J. Organ. Chem.,21, 3819 (1962).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1354–1355, June, 1967.

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Eremenko, L.T., Korolev, A.M. The O-nitration of tertiary unsaturated alcohols andα-epoxyalcohols. Russ Chem Bull 16, 1303–1304 (1967). https://doi.org/10.1007/BF00908297

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Keywords

  • Alcohol
  • Nitrate
  • Tertiary Alcohol
  • Unsaturated Alcohol