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Some reactions of diethylN-alkyl-N-Hydroxymethylphosphoramidates

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  1. 1.

    The condensation of diethyl N-alkyl-N-hydroxymethylphosphoramidates (alkyl groups — ethyl, propyl, butyl) with methyl alcohol and with propyl, isopropyl, and butyl mercaptans has given the corresponding N-alkyl-N-methoxymethyl and N-alkyl-N-alkylthiomethyl derivatives of diethyl phosphoramidate, and these compounds have been characterized.

  2. 2.

    The reaction of acetyl chloride with the N-ethyl and N-butyl derivatives of diethyl N-hydroxymethylphosphoramidate has given the corresponding N-alkyl-N-acetoxymethylphosphoramidates.

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Literature cited

  1. 1.

    P. I. Alimov and O. N. Fedorova, Izd. AN SSSR, Ser. khim.,1966, 1461.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1348–1350, June, 1967.

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Fedorova, O.N., Alimov, P.I. Some reactions of diethylN-alkyl-N-Hydroxymethylphosphoramidates. Russ Chem Bull 16, 1296–1297 (1967).

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  • Alcohol
  • Methyl
  • Chloride
  • Ethyl
  • Diethyl