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Study of tetraalkylammonium tetraalkylaluminum complexes R4NAlR4

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Conclusions

Complexes of the type R4NAl(C2H5)4 have been obtained by the action of a tetraalkylammonium halide on an alkali-metal tetraethylaluminate. The reaction is catalyzed by triethylaluminum.

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Literature cited

  1. 1.

    L. I. Zakharkin and V. V. Gavrilenko, Zh. Obshch. Khim.,32, 689 (1962).

  2. 2.

    H. Lehmkuhl, Angevv Chem.,75, 22, 1095 (1963).

  3. 3.

    K. Ziegler, R. Koester, H. Lehmkuhl, and K. Beinert, Ann. Chem. 629, 33 (1960).

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1380–1381, June 1969.

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Gavrilenko, V.V., Karaksin, Y.N. & Zakharkin, L.I. Study of tetraalkylammonium tetraalkylaluminum complexes R4NAlR4 . Russ Chem Bull 18, 1280–1281 (1969). https://doi.org/10.1007/BF00908192

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Keywords

  • Halide
  • Triethylaluminum
  • Tetraalkylammonium Halide