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Fluorine-containingβ-sultones

Communication 28. Reactions of β-sultones with ethylene oxide

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Conclusions

  1. 1.

    The reactions of tetrafluoro-1,2-ethanesultone and of hexafluoro-2,1-propanesultone with ethylene oxide follow the general type of the reactions of fluorine-containingβ-sultones with nucleophilic reagents.

  2. 2.

    Difluorosulfoacetic acid bis-2-fluoroethyl ester, 2-fluoroethyl difluoro(fluorosulfonyl)acetate, and 2-fluoroethyl tetrafluoro-2-(fluorosulfonyl)propionate were prepared.

  3. 3.

    By the reactions of polyfluoro-2-(fluorosulfonyl)alkanoyl fluorides with 2-fluoroethanol and with 2-chloroethanol the corresponding 2-haloethyl polyfluoro-2-(fluorosulfonyl)alkanoates were prepared.

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Literature cited

  1. 1.

    G. A. Sokol'skii, M. A. Belaventsev, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim.,1967, 1524.

  2. 2.

    M. A. Belaventsev, G. A. Sokol'skii, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim.,1965, 1655.

  3. 3.

    I. L. Knunyants, Dokl. Akad. Nauk SSSR,55, 227 (1947); I. L. Knunyants, O. V. Kil'disheva, and É. G. Bykovskaya, Dokl. Akad. Nauk SSSR,57, 49 (1947).

  4. 4.

    M. A. Dmitriev, G. A. Sokol'skii, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk,1960, 847.

  5. 5.

    L. I. Ragulin, P. P. Ropalo, G. A. Sokol'skii, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim.,1967, 1754.

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1565–1570, July, 1968.

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Sokol'skii, G.A., Belaventsev, M.A., Markov, L.A. et al. Fluorine-containingβ-sultones. Russ Chem Bull 17, 1470–1474 (1968). https://doi.org/10.1007/BF00907846

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Keywords

  • Oxide
  • Acetate
  • Ethylene
  • Ester
  • Propionate