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Halogenation of vinyloxyanilines

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Conclusions

  1. 1.

    Chlorine and bromine add in the cold to vinyloxyanilines at the double bond of the vinyl group.α, β-Dibromo-o-,α, β-dibromo-m-,α, β-dibromo-p-phenetidines,α, β-dichloro-o-phenetidine, andα, β- dibromo-p-phenacetin were synthesized.

  2. 2.

    With an excess of bromine the reaction goes further to formα, β, β-tribromophenetidines.

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Literature cited

  1. 1.

    A. V. Kalabina, A. Kh. Filippova, E. S. Domina, et al., Izv. SO Akad. Nauk SSSR, 1958 p. 9.

  2. 2.

    K. Nakanisi, Infrared Spectra and Structure of Organic Compounds [Russian translation], Mir (1965).

  3. 3.

    M. F. Shostakovskii, G. G. Skvortzova, M. Ya. Samoilova, and Yu. F. Faershtein, Zh. Obshch. Khim.,31, 3226 (1961).

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2833–2835, December, 1968.

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Shostakovskii, M.F., Skvortsova, G.G., Kurov, G.N. et al. Halogenation of vinyloxyanilines. Russ Chem Bull 17, 2688–2689 (1968). https://doi.org/10.1007/BF00907808

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Keywords

  • Chlorine
  • Double Bond
  • Vinyl
  • Bromine
  • Halogenation