The thermal decomposition of fluorochloro-, fluorobromo-, and fluoroiododinitromethane in the gas phase was studied.
The results obtained are in accord with the previously established principles of the effect of halogen substituents on the dissociation energy of the C-N bond and the rate of decomposition of aliphatic nitro compounds.
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G. M. Nazin, G. B. Manelis, and F. I. Dubovitskii, DAN SSSR,177, 1387 (1968).
G. M. Nazin, G. B. Manelis, and F. I. Dubovitskii, Izv. AN SSSR, Ser. Khim.,1968, 2629.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2801–2803, December, 1968.
The authors express their thanks to Ya. G. Legin and A. A. Fainzil'berg for furnishing the compounds for investigation.
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Nazin, G.M., Manelis, G.B. & Dubovitskii, F.I. Thermal decomposition of fluorochloro-dinitromethane and related compounds. Russ Chem Bull 17, 2650–2651 (1968). https://doi.org/10.1007/BF00907793
- Thermal Decomposition
- Related Compound
- Dissociation Energy
- Nitro Compound