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Reaction of keto alcohols with organophosphorus compounds

Communication 1. Reaction ofβ-keto alcohols with dialkyl chlorophosphites

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Conclusions

  1. 1.

    3-Ketoalkyl dialkyl phosphites were obtained by the reaction ofβ-keto alcohols with dialkyl chlorophosphites in the presence of a base.

  2. 2.

    A study was made of the reaction of 3-ketoalkyl dialkyl phosphites with sulfur and with nitrogen oxides.

  3. 3.

    Diethyl 3-ketobutyl phosphite was reacted with chloral and dibutyl 3-ketobutyl phosphite was reacted with acetyl chloride.

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Literature cited

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2755–2761, December, 1968.

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Rizpolozhenskii, N.I., Mukhametov, F.S. Reaction of keto alcohols with organophosphorus compounds. Russ Chem Bull 17, 2609–2614 (1968). https://doi.org/10.1007/BF00907784

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Keywords

  • Oxide
  • Nitrogen
  • Alcohol
  • Sulfur
  • Chloride