The authors have made a kinetic study of nucleophilic replacement of chlorine by an amino group in derivatives of bischloromethylphosphinic acid. The process takes place by an SN1-mechanism in the case of weak nucleophilic reagents (the aniline type) and by an Sn2-mechanism in the case of strong nucleophilic reagents (benzylamine type).
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M.K. Il'ina and I.M. Shermergorn, Izv. Akad. Nauk SSSR, Ser. Khim., 1346 (1967).
M.K. Il'ina and I.M. Shermergorn, Izv. Akad. Nauk SSSR, Ser. Khim., 1860 (1968).
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 175–177, January, 1969.
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Il'ina, M.K., Shermergorn, I.M. Kinetics of reactions of derivatives of bischloromethylphosphinic acid with amines. Russ Chem Bull 18, 170–171 (1969). https://doi.org/10.1007/BF00907627
- Kinetic Study
- Nucleophilic Reagent