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Influence of the fluorine pressure on the rate of its interaction with silicon

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  1. 1.

    The rate of interaction of silicon with fluorine at room temperature increases as a linear function of the pressure.

  2. 2.

    At fluorine pressures equal to 100 mm and above, a substantial increase in the reaction rate is observed, leading in certain cases even to fusion of the sample.

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Literature cited

  1. 1.

    V. V. Tyapkina and N. S. Guseva, Zh. Fiz. Khimii,40, 1064 (1966).

  2. 2.

    V. A. Arslambekov, K. M. Gorbunov, and N. S. Guseva, Izv. Akad. Nauk SSSR, Neorgan. Mat.,2, 1343 (1966).

  3. 3.

    A. K. Kuriakose and J. L. Margrave, J. Phys. Chem.,68, 2671 (1964).

  4. 4.

    V. A. Arslambekov, in: Mechanism of the Interaction of Metals with Gases [in Russian], Nauka (1964), p. 167.

  5. 5.

    I. G. Ryss, The Chemistry of Fluorine and Its Inorganic Compounds [in Russian], Goskhimizdat (1956).

  6. 6.

    V. A. Arslambekov and M. V. Ivanov, Izv. Akad. Nauk SSSR, Ser. Khim., 2157 (1969).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 80–85, January, 1969.

In conclusion, the authors would like to express the irgratitude to M. V. Ivanov and P. K. Mogilevtsev for their aid in conducting the mass spectrometric and electron-diffraction studies.

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Arslam'ekov, V.A., Gorbunova, K.M. & Guseva, N.S. Influence of the fluorine pressure on the rate of its interaction with silicon. Russ Chem Bull 18, 69–72 (1969). https://doi.org/10.1007/BF00907596

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  • Silicon
  • Linear Function
  • Temperature Increase
  • Fluorine
  • Room Temperature Increase