The decomposition of Mannich bases occurs according to the mechanism that we had demonstrated earlier. The decomposition constants were determined for 1-methylamino-2-methyl-2-nitropropane, 1-din-propylamino-2-methyl-2-nitropropane, 1-dimethylamino-2-ethyl-2-nitrobutane, and 1-diethylamino-2-ethyl-2-nitrobutane.
The deciding role of steric factors in the decomposition of Mannich bases was demonstrated.
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M. M. Bolgaya, Yu. N. Belokon', N. S. Martinkova, and V. M. Belikov, Izv. Akad. Nauk SSSR, Ser. Khim., 2234 (1967).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 74–80, January, 1969.
The article is published on the basis of a Resolution of the Conference of Editors-in-Chief of the Journals of the Academy of Sciences of the USSR from July 12, 1962, as the dissertation work of M. M. Dolgaya.
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Dolgaya, M.M., Belokon', Y.N. & Belikov, V.M. Influence of steric factors on the rate of decomposition of Mannich bases. Russ Chem Bull 18, 63–68 (1969). https://doi.org/10.1007/BF00907595
- Decide Role
- Steric Factor
- Mannich Base
- Decomposition Constant