The velocity constants of the cycloaddition of 3-nitroisoxazoline N-oxide to styrene in various solvents have been determined.
The velocity constants of the cycloaddition of 3-nitroisoxazoline N-oxide to hex-1-ene, methyl acrylate, and vinyl ethyl ether in dioxane have been determined.
The cycloaddition of 3-nitroisoxazoline N-oxide to olefins is a multicenter synchronous process.
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V. A. Tartakovskii, I. E. Chlenov, S. S. Smagin, and S. S. Novikov, Izv. AN SSSR, Ser. khim.,1964, 583.
R. Huisgen, Angew. Chem.,75, 742 (1963).
V. A. Tartakovskii, A. A. Onishchenko, V. A. Smirnyagin, and S. S. Novikov, Zh. organ, khimii,2, 2095 (1966).
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 177–179, January, 1967.
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Tartakovskii, V.A., Onishchenko, A.A. & Novikov, S.S. Mechanism of the 1,3-dipolar cycloaddition of nitrone ethers. Russ Chem Bull 16, 166–168 (1967). https://doi.org/10.1007/BF00907123