In the joint dehydration of butanol-2 and radiocarbon C14- labeled butanol-1 over fluorinated aluminum oxide, butene-1 and butenes-2 are obtained directly from butanol-2; in addition, there is an isomerization of butene-1, with the direct formation both of cis- and of trans-butene-2.
In the dehydration of butanol-1, n-dibutyl ether is formed, its yield passing through a maximum as the experimental temperature is varied.
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G. V. Isagulyants, Yu. I. Derbentsev, E. I. Klabunovskii, and A. A. Balandin, Izv. AN SSSR, Ser. Khim.,1964, 985.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 42–46, January, 1967.
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Isagulyants, G.V., Derbentsev, Y.I. & Balandin, A.A. Investigation of the mechanism of the dehydration of butanol-2 over fluorinated aluminum oxide using radiocarbon C14 . Russ Chem Bull 16, 37–40 (1967). https://doi.org/10.1007/BF00907093
- Experimental Temperature