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Investigation of the mechanism of the dehydration of butanol-2 over fluorinated aluminum oxide using radiocarbon C14

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Conclusions

  1. 1.

    In the joint dehydration of butanol-2 and radiocarbon C14- labeled butanol-1 over fluorinated aluminum oxide, butene-1 and butenes-2 are obtained directly from butanol-2; in addition, there is an isomerization of butene-1, with the direct formation both of cis- and of trans-butene-2.

  2. 2.

    In the dehydration of butanol-1, n-dibutyl ether is formed, its yield passing through a maximum as the experimental temperature is varied.

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Literature cited

  1. 1.

    G. V. Isagulyants, Yu. I. Derbentsev, E. I. Klabunovskii, and A. A. Balandin, Izv. AN SSSR, Ser. Khim.,1964, 985.

  2. 2.

    A. L. Klyachko-Gurvich, Izv. AN SSSR, Otd. Khim. N.,1961, 1884.

  3. 3.

    G. V. Isagulyants, A. A. Balandin, E. I. Popov, and Yu. I. Derbentsev, Zh. Fiz. Khimii,38, 20 (1964).

  4. 4.

    A. A. Balandin, G. V. Isagulyants, E. I. Popov, Yu. I. Derbentsev, and S. L. Vinogradov, Izv. AN SSSR, Otd. Khim. N.,1958, 233.

  5. 5.

    Yu. I. Derbentsev, G. V. Isagulyants, and A. A. Balandin, Zh. Fiz. Khimii,39, 2611 (1965).

  6. 6.

    J. E. Kilpatrick, E. J. Prosen, K. S. Pitzer, and F. D. Rossini, J. Res. Nat. Bur. Standards,36, 595 (1964).

  7. 7.

    A. J. Lundeen and R. Van Hoozer, J. Amer. Chem. Soc.,85, 2180 (1963).

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 42–46, January, 1967.

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Isagulyants, G.V., Derbentsev, Y.I. & Balandin, A.A. Investigation of the mechanism of the dehydration of butanol-2 over fluorinated aluminum oxide using radiocarbon C14 . Russ Chem Bull 16, 37–40 (1967). https://doi.org/10.1007/BF00907093

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Keywords

  • Oxide
  • Aluminum
  • Ether
  • Dehydration
  • Experimental Temperature