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Chloride complexes of rhodium (III) in aqueous solutions

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Conclusions

  1. 1.

    The process of complex formation of rhodium with the chloride ion in aqueous solutions is stepwise and reversible.

  2. 2.

    On the basis of the spectrophotometric data, using perchlorate solutions of rhodium, we calculated the total and stepwise stability constants of rhodium chloride complexes.

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Literature cited

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    O.A. Efremenko, V. I. Shlenskaya, and I. P. Alimarin, Izv. Akad. Nauk SSSR, Ser. Khim., 740 (1969).

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    Synthesis of Complex Compounds of Metals of the Platinum Group, Handbook [in Russian], Nauka (1964), p. 256.

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    F. Rossotti and H. Rossotti, Determination of the Stability Constants and Other Equilibrium Constants in Solutions [Russian translation], Mir (1965), p. 139.

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    F. Rossotti, in: Modern Chemistry of Coordination Compounds [Russian translation], IL (1963), p. 42.

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1643–1646, August, 1969. Original article submitted July 8, 1968.

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Shlenskaya, V.I., Efremenko, O.A., Oleinikova, S.V. et al. Chloride complexes of rhodium (III) in aqueous solutions. Russ Chem Bull 18, 1525–1527 (1969). https://doi.org/10.1007/BF00906372

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Keywords

  • Chloride
  • Aqueous Solution
  • Complex Formation
  • Perchlorate
  • Stability Constant