The process of complex formation of rhodium with the chloride ion in aqueous solutions is stepwise and reversible.
On the basis of the spectrophotometric data, using perchlorate solutions of rhodium, we calculated the total and stepwise stability constants of rhodium chloride complexes.
This is a preview of subscription content, log in to check access.
Buy single article
Instant access to the full article PDF.
Price includes VAT for USA
Subscribe to journal
Immediate online access to all issues from 2019. Subscription will auto renew annually.
This is the net price. Taxes to be calculated in checkout.
E. Blasius and W. Preetz, Z. Anorgan. und Allgem. Chem.,335, 1 (1965).
A.V. Belyaev and E.V. Ptitsyn, Zh. Obshch. Khim.,35, 1887, 72124 (1965).
W.C. Wolsey, Ch.A. Reynolds, and J. Kleinberg, Inorgan. Chem.,2, 463 (1963).
D. Cozzi and F. Pantani, J. Inorg. and Nucle. Chem.,8, 385 (1958).
O.A. Efremenko, V. I. Shlenskaya, and I. P. Alimarin, Izv. Akad. Nauk SSSR, Ser. Khim., 740 (1969).
Synthesis of Complex Compounds of Metals of the Platinum Group, Handbook [in Russian], Nauka (1964), p. 256.
F. Rossotti and H. Rossotti, Determination of the Stability Constants and Other Equilibrium Constants in Solutions [Russian translation], Mir (1965), p. 139.
K.B. Yatsimirskii and L.I. Budarin, Zh. Neorgan. Khimii,7, 1090 (1962).
F. Rossotti, in: Modern Chemistry of Coordination Compounds [Russian translation], IL (1963), p. 42.
K.Z. Bridges and J. C. Chang, Inorgan. Chem.,6, 619 (1967).
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1643–1646, August, 1969. Original article submitted July 8, 1968.
About this article
Cite this article
Shlenskaya, V.I., Efremenko, O.A., Oleinikova, S.V. et al. Chloride complexes of rhodium (III) in aqueous solutions. Russ Chem Bull 18, 1525–1527 (1969). https://doi.org/10.1007/BF00906372
- Aqueous Solution
- Complex Formation
- Stability Constant