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The catalytic hydrocondensation of carbon monoxide with olefins and their hydropolymeriza tion under the influence of carbon monoxide and hydrogen

Communication 32. Conversion of octene-1

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Summary

  1. 1.

    The catalytic conversion of octene-1 in the presence of hydrogen and of a mixture of hydrogen and carbon monoxide was investigated.

  2. 2.

    Under optimum conditions up to 30% of octene -1 underwent reaction with formation of intermediate hydrocarbons from C9 to C16 as well as of higher boiling components.

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Literature cited

  1. 1.

    Ya. T. Eidus and N. I. Ershov, Izv. AN SSSR, Otd. khim. n. 1655 (1959). Problemy Kinetiki i Kataliza,10, 404 (I960).

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    Ya. T. Eidus, N. D. Zelinskii, K. V. Puzitskii. and N. I. Ershov. Ivz. AN SSSR, Otd. khim. n. 145 (1952).

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    Ya. T. Eidus and R. I. Izmailov. Izv. AN SSSR. Otd. khim. n. 467 (1956).

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    Ya. T. Eidus, N. I. Ershov, and E. M. Terent'eva, Izv. AN SSSR Otd. khim. n.882 (1954); N. E. Ershov and N. E. Ershov, Ya. T. Eidus, and V. R. Erokhina, Izv. AN SSSR Otd. khim. n. 366 (1960).

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    A. J. van Pelt, Jr and J. P. Wibaut, Rec. Trav. chim.60, 55 (1941).

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    R. D. Obolentsev, Physical Constants of Hydrocarbons, Liquid Fuels and Oils [in Russian] Gostoptekhizdat, Moscow-Leningrad, 1953.

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    Ya. T. Eidus, N. I. Ershov, K. V. Puzitskii, and I. V. Guseva, Izv. AN SSSR, Otd. khim. n. 913 (1960).

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Ershov, N.I., Eidus, Y.T. & Erokhina, V.R. The catalytic hydrocondensation of carbon monoxide with olefins and their hydropolymeriza tion under the influence of carbon monoxide and hydrogen. Russ Chem Bull 10, 1580–1585 (1961). https://doi.org/10.1007/BF00906159

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Keywords

  • Hydrogen
  • Hydrocarbon
  • Optimum Condition
  • Carbon Monoxide
  • Boiling