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Influence of solvents on the direction of the addition of mercury salts of trinitromethane to unsaturated compounds

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Conclusions

  1. 1.

    The addition of the Hg salt of trinitromethane to olefins both in polar proton and aprotic solvents and in nonpolar solvents takes place in the same way, with the C-alkylation of the trinitromethane anion.

  2. 2.

    The stereochemistry of the addition of the Hg salt of trinitromethane to olefins is also the same in these solvents.

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Literature cited

  1. 1.

    S. S. Novikov, T. I. Godovikova, and V. A. Tartakovskii, Dokl. AN SSSR,124, 334 (1959).

  2. 2.

    V. A. Tartakovskii, S. S. Novikov, and T. I. Godovikova, Izv. AN SSSR, Otd. khim. n.,1961, 1042.

  3. 3.

    V. I. Slovetskii, V. A. Tartakovskii, and S. S. Novikov, Izv. AN SSSR, Otd. khim. n.,1962, 1400.

  4. 4.

    N. S. Zefirov, Uspekhi khimii,34, 1272 (1965).

  5. 5.

    I. E. Chlenov, Thesis, Moscow (1965).

  6. 6.

    V. A. Tartakovskii, L. A. Nikonova, and S. S. Novikov, Izv. AN SSSR, ser. khim.,1966, 1290.

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 706–708, March, 1967.

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Tartakovskii, V.A., Nikonova, L.A. & Novikov, S.S. Influence of solvents on the direction of the addition of mercury salts of trinitromethane to unsaturated compounds. Russ Chem Bull 16, 690–691 (1967). https://doi.org/10.1007/BF00906029

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Keywords

  • Mercury
  • Nonpolar Solvent
  • Aprotic Solvent
  • Unsaturated Compound
  • Polar Proton