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Investigation of the tautomerism and geometric isomerism of nitrogen-containing derivatives of carbonyl compounds

Communication 3. Polarographic investigation of some semi- and thiosemicarbazones in aqueous-alcoholic solutions

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Summary

By means of polarographic and microcoulometric methods it was shown that the reduction of semi- and thiosemicarbazones of acetophenone, p-chloroacetophenone and p-aminoacetophenone and also benzophenone semicarbazone at a dropping mercury electrode takes place irreversibly with participation of two electrons.

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Kitaev, Y.P., Budnikov, G.K. & Arbuzov, A.E. Investigation of the tautomerism and geometric isomerism of nitrogen-containing derivatives of carbonyl compounds. Russ Chem Bull 10, 762–768 (1961). https://doi.org/10.1007/BF00905942

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Keywords

  • Mercury
  • Carbonyl
  • Carbonyl Compound
  • Acetophenone
  • Benzophenone