By the action of tributyl borate on tricarbonyl(lithiocyclopentadienyl)manganese and -rhenium the corresponding boronic acids were prepared.
Some properties of these acids were studied. In an aqueous medium they are readily hydrolyzed with formation, respectively, of tricarbonylcyclopentadienylmanganese (TCM) and tricarbonyicyclopentadienylrhenium (TCR), and under given conditions the rate of hydrolysis of TCR-boronic acid is higher than the rate of hydrolysis of TCM-boronic acid.
The chloro and bromo derivatives of TCR and the already-known similar derivatives of TCM were prepared by the action of cupric halides on symmetrical mercury derivatives of TCM and TCR.
Bromo derivatives of TCM and TCR are inert in nucleophilic exchange reactions of halogen.
This is a preview of subscription content, log in to check access.
Buy single article
Instant access to the full article PDF.
Price includes VAT for USA
Subscribe to journal
Immediate online access to all issues from 2019. Subscription will auto renew annually.
This is the net price. Taxes to be calculated in checkout.
E.O. Fischer and A. Maasböl, Chem. Ber.,100, 2445 (1967).
E.O. Fischer and A. Riedel, Chem. Ber.,101, 156 (1968).
A.N. Nesmeyanov, K.N. Anisimov, N.E. Kolobova, and Yu.V. Makarov, Dokl. Akad. Nauk SSSR,178, 1331 (1968).
A.N. Nesmeyanov, K.N. Anisimov, N.E. Kolobova, and Yu.V. Makarov, Izv. Akad. Nauk SSSR, Ser. Khim.,1968, 686.
N.E. Kolobova and Yu.V. Makarov, Izv. Akad. Nauk SSSR, Ser. Khim.,1968, 2529.
A.N. Nesmeyanov, V.A. Sazonova, and V.N. Drozd, Dokl. Akad. Nauk SSSR,126, 1004 (1959).
W. Gerrard, Organic Chemistry of Boron [Russian translation], Izd. Khimiya, (1966).
L.I. Denisovich, Dissertation [in Russian], Moscow (1968).
A.N. Nesmeyanov, K.N. Anisimov, and Z.P. Valueva, Izv. Akad. Nauk SSSR, Ser. Khim.,1962, 1683.
A.N. Nesmeyanov, N.E. Kolobova, K.N. Anisimov, and L.I. Baryshnikov, Izv. Akad. Nauk SSSR, Ser. Khim.,1964, 1135.
A.N. Nesmeyanov, V.A. Sazonova, and V.N. Drozd, Dokl. Akad. Nauk SSSR,129, 1060 (1959).
G.A. Razuvaev and M.S. Fedorov, Zh. Obshch. Khim.,22, 484 (1952).
G.A. Razuvaev and M.S. Fedorov, in: Collection of Papers on Organic Chemistry [in Russian], Vol. 2, Izd. Akad. Nauk SSSR (1953), p. 1517. 14. G.A. Razuvaev, M.S. Fedorov, T.N. Zaichenko, and N.A. Kul'vinskaya, ibid., p. 1514.
A.N. Nesmeyanov, É.G. Perevalova, and O.A. Nesmeyanova, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk,1962, 47.
M. Cais and N. Narkis, J. Organometal. Chem.,3, 269 (1965).
V.A. Nefedov, Zh. Obshch. Khim.,39, 665 (1969).
A.N. Nesmeyanov, V.A. Sazonova, and V.N. Drozd, Dokl. Akad. Nauk SSSR,137, 102 (1961).
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, no. 9, pp. 1992–1996, September, 1969.
About this article
Cite this article
Nesmeyanov, A.N., Kolobova, N.E., Makarov, Y.V. et al. Borono and halo derivatives of tricarbonylcyclopentadienylmanganese and -rhenium. Russ Chem Bull 18, 1842–1845 (1969). https://doi.org/10.1007/BF00905820
- Exchange Reaction