The fluorine-containing ketones of cyclopentadienylmanganesetricarbonyl, (CO)3MnC5H4COCF3 and (CO)3MnC5H4COC3F7, were synthesized and characterized by their IR and PMR spectra.
The following reactions of (CO)3MnC5H4COCF3 were studied: the fluoroform reaction, reduction with lithium aluminum hydride, and reaction with Grignard reagents.
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R. Riemschneider and K. Petzoldt, Z. Naturforsch.,15b, 627 (1960).
A. N. Nesmeyanov, K. N. Anisimov, N. E. Kolobova, and I. B. Zlotina, Dokl. Akad. Nauk SSSR,154, 391 (1964).
A. N. Nesmeyanov, K. N. Anisimov, N. E. Kolobova, and G. K. I. Magomedov, Dokl. Akad. Nauk SSSR,158, 163 (1964).
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 901–902, April, 1968.
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Nesmeyanov, A.N., Anisimov, K.N., Kolobova, N.E. et al. Synthesis and some properties of fluorine-containing ketone derivatives of cyclopentadienylmanganesetricarbonyl. Russ Chem Bull 17, 861–862 (1968). https://doi.org/10.1007/BF00905770
- Lithium Aluminum