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Catalysis of hydrogen transfer by methods believed to be similar to enzymatic methods

Communication 9. Catalysts and catalytic systems including π-acceptors

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Conclusions

  1. 1.

    Organic catalysts of theπ-acceptor type of the reduction of 2,2,6,6-tetramethylpiperidone-4-oxy-1 with 2,6-dimethyl-3,5-dicarbethoxy-1,4-dihydropyridine were found.

  2. 2.

    Catalytic systems includingπ-acceptors were produced. In the presence of the catalytic system ofπ-acceptor and o-naphthoquinone, the reduction of 2,2,6,6-tetramethylpiperidone-4-oxy-1, nitro-compounds, and molecular oxygen with dihydropyridine compounds and cyclohexadiene-1,4 can be conducted.

  3. 3.

    The kinetics of the catalytic reduction of 2,2,6,6-tetramethylpiperidone-4-oxy-l was investigated. It was proposed that the mechanism of the action of the indicated catalysts and catalytic systems involves the formation ofπ-complexes including a reducing agent as the donor.

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 347–356, February, 1969.

The authors would like to thank N. S. Zaitsev for his aid in the experimental work, A. S. Astakhov for providing the 7,7,8,8-tetracyanoquinodimethane and tetracyanoethylene, D. D. Mozzhukhin for providing the 2,2,6,6-tetramethylpiperidone-4-oxy-1, and É. B. Yagubskii for providing the p-phenyldimalanonitrile.

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Zelenin, S.N., Gol'dshleger, N.F. & Khidekel', M.L. Catalysis of hydrogen transfer by methods believed to be similar to enzymatic methods. Russ Chem Bull 18, 300–307 (1969). https://doi.org/10.1007/BF00905539

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Keywords

  • Oxygen
  • Hydrogen
  • Catalysis
  • Molecular Oxygen
  • Catalytic System