Advertisement

Springer Nature is making Coronavirus research free. View research | View latest news | Sign up for updates

Addition of aldehydes to unsaturated compounds induced by autooxidation

  • 69 Accesses

  • 6 Citations

Conclusions

  1. 1.

    The radical addition of aliphatic aldehydes to various unsaturated compounds, initiated by autooxidation, was studied.

  2. 2.

    The mechanism of initiation by oxygen in the presence of cobalt salts and without the participation of a catalyst was discussed.

This is a preview of subscription content, log in to check access.

Literature cited

  1. 1.

    G. I. Nikishin, M. G. Vinogradov, and B. V. Kereselidze, Izv. Akad. Nauk SSSR, Ser. Khim., 1624 (1967).

  2. 2.

    O. P. Yablonskii, M. G. Vinogradov, R. V. Kereselidze, and G. I. Nikishin, Izv. Akad. Nauk SSSR, Ser. Khim., 318 (1969).

  3. 3.

    H. R. Cooper and H. W. Melvill, J. Chem. Soc., 1984 (1951).

  4. 4.

    N. M. Émanuél', E. T. Denisov, and Z. K. Maizus, Chain Reactions of Liquid-Phase Oxidation of Hydrocarbons [in Russian], Nauka (1965), p. 84.

  5. 5.

    G. I. Nikishin, M. G. Vinogradov, and B. V. Kereselidze, Izv. Akad. Nauk SSSR, Ser. Khim., 1122 (1966).

  6. 6.

    G. I. Nikishin, M. G. Vinogradov, and R. V. Kereselidze, Zh. Organ. Khim.,2, 1918 (1966).

  7. 7.

    F. W. Stasy and J. F. Harris, Organic Reactions [Russian translation], Vol. 13, Mir (1966), p. 170.

  8. 8.

    J. d'Ans and W. Frey, Ber.,45, 1845 (1912).

  9. 9.

    E. C. Ladd, USA Patent No. 2533944; Chem. Abstrs.,45, 4741 (1951).

  10. 10.

    E. C. Ladd, USA Patent No. 2560770; Chem. Abstrs.,46, 9584d (1952).

  11. 11.

    Great Britain Patent No. 636287; Chem. Abstrs.,44, 7870d (1950).

Download references

Author information

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 322–328, February, 1969.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Vinogradov, M.G., Kereselidze, R.V., Gachechiladze, G.G. et al. Addition of aldehydes to unsaturated compounds induced by autooxidation. Russ Chem Bull 18, 276–281 (1969). https://doi.org/10.1007/BF00905535

Download citation

Keywords

  • Oxygen
  • Cobalt
  • Aldehyde
  • Radical Addition
  • Unsaturated Compound