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On the reaction of diethylanilido phosphite with 2-diethylaminomethyl-6-methylphenol

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  1. 1.

    The reaction of diethylanilidophosphite with 2-diethylaminomethyl-6-methylphenol gives 2-oxo-2-ethoxy-7-methyl-1-oxa-2-phosphaindan (I), 2-oxo-2-anilido-7-methyl-1-oxa-2-phosphaindan (II), and 2-oxo-2-(2′-methyl-6′-diethylaminomethyl)phenoxy-7-methyl-1-oxa-2-phosphaindan (III).

  2. 2.

    The reaction of 2-diethylaminomethyl-6-methylphenol with 2-oxo-2-diethylamido-7-methyl-1-oxa-2-phosphaindan gives 2-oxo-2-(2′-methyl-6′-diethylaminomethyl)phenoxy-7-methyl-1-oxa-2-phosphaindan, which is converted by heat to 3′,9″-dimethyl-2,3,5,6-dibenzo-7a-oxo-1,7-dioxa-7a-phosphatetrahydroindan.

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Literature cited

  1. 1.

    B. E. Ivanov and L. A. Valitova, Authors' certificate No. 183747 (1966); Byull. izobr., No. 14 (1966).

  2. 2.

    B. E. Ivanov and L. A. Valitova, Izv. AN SSSR, Ser. khim.,1967, 1087.

  3. 3.

    M. I. Kabachnik and V. A. Gilyarov, DAN SSSR,96, 991 (1954).

  4. 4.

    L. Bellamy, The Infrared Spectra of Complex Molecules [Russian translation], IL (1963).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1600–1602, July, 1967.

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Ivanov, B.E., Ageeva, A.B. & Pasmanyuk, S.V. On the reaction of diethylanilido phosphite with 2-diethylaminomethyl-6-methylphenol. Russ Chem Bull 16, 1539–1540 (1967). https://doi.org/10.1007/BF00905368

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