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Kraftfeld- und CNDO-Rechnungen von Vanadium-N-chlorimid-trichlorid CINVCL3

Force constants and CNDO calculations on N-chlorimido-vanadium (V) trichloride

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Abstract

Force field and CNDO calculations were performed on CINVCl3. These results give some evidence for the large CINV bond angle and the short CIN distance. One can conclude that for the CIN bond a large π contribution must be assumed.

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Kosmus, W., Kalcher, K. Kraftfeld- und CNDO-Rechnungen von Vanadium-N-chlorimid-trichlorid CINVCL3 . Monatshefte für Chemie 112, 917–924 (1981). https://doi.org/10.1007/BF00905063

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Keywords

  • N-Chlorimido-vanadium(V) trichloride
  • Force Constants
  • CNDO calculations