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Relative reactivity of unsaturated germanium compounds in reactions with methyl radicals

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Conclusions

  1. 1.

    The reactivity of the multiple bond towards methyl radicals decreases in the order (CH3)3SiCH=CH2 > (CH3)3CCH=CH2 > (CH3)3GeCH=CH2.

  2. 2.

    Removal of a hydrogen atom from the “allyl ” position assumes considerable importance for α- and β-methyl-substituted vinylgermanes.

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Literature cited

  1. 1.

    N. S. Nametkin, S. G. Durgar'yan, L. I. Tikhonova, N. V. Ushkov, and M. V. Pozdnyakova, DAN SSSR,181, No. 6 (1968).

  2. 2.

    N. S. Nametkin, S. G. Durgar'yan, and L. I. Tikhonova, DAN SSSR,172, 615 (1967).

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    N. S. Nametkin, S. G. Durgar'yan, and L. I. Tikhonova, DAN SSSR,172, 867 (1967).

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    S. I. Beilin, N. A. Pokatilo, and B. A. Dolgoplosk. Vysokomolekul. Soed.,7, 1085 (1965).

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    V. V. Korshak, A. M. Polyakova, V. F. Mironov, and A. D. Petrov, Izv. AN SSSR, Otd. Khim. Nauk,1959, 178.

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    M. Kanazashi, Bull. Chem. Soc. Japan,28, 44 (1955).

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    D. Scifert, Organometallic Compounds with a Vinyl Group [in Russian], Mir (1964), p. 26.

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    R. P. Buckley, F. Leavitt, and M. Schwartz, J. Amer. Chem. Soc.,78, 5557 (1956).

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    L. Herk, A. Stefani, and M. Schwarz, J. Amer. Chem. Soc.,83, 3008 (1961).

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, No. 9, pp. 2139–2141, September, 1968.

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Nametkin, N.S., Beilin, S.I., Tikhonova, L.I. et al. Relative reactivity of unsaturated germanium compounds in reactions with methyl radicals. Russ Chem Bull 17, 2032–2033 (1968). https://doi.org/10.1007/BF00905014

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Keywords

  • Hydrogen
  • Methyl
  • Hydrogen Atom
  • Germanium
  • Allyl