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Proton magnetic resonance spectra of benzylmercury halides

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Conclusions

  1. 1.

    On the basis of the data obtained for non symmetrical benzyl derivatives of mercury, it was hypothesized that the ionic character of the C-Hg bonds increases in the series iodide < bromide < chloride < acetate.

  2. 2.

    In a study of the PMR spectra of a number of o-, m-, and p-substituted benzylmercury chlorides, it was shown that the shielding of the methylene protons increases in the series: o-NO2 < p-NO2 < H < m-andp-F < m-Cl, p-CH3 < p-Cl, m- and p-Br, m-CH3 < 3, 5-di-CH3 < o-Cl < o-F, o-CH3 < 2, 6-di-CH3 < 2, 4, 6-tri-CH3.

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Literature cited

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    I. P. Beletskaya, T. P. Fetisova, and O. A. Reutov, Dokl. Akad. Nauk SSSR,155, 1095 (1964); A. Kalyavin, T. A. Smolina, and O. A. Reutov, Dokl. Akad. Nauk SSSR,157, 919 (1964); Yu. G. Bundel', N. D. Antonova, and O. A. Reutov, Dokl. Akad. Nauk SSSR,166, 1103 (1966).

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    Yu. A. N. Pentin, I. P. Beletskaya, B. Praisnar, and O. A. Reutov, Izv. Akad. Nauk SSSR, Ser. Khim., 1180 (1965).

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    N. D. Antonova, Dissertation [in Russian], Moscow (1965).

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    V. S. Petrosyan and O. A. Reutov, Dokl. Akad. Nauk SSSR,180, 876 (1968).

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    K. L. Williamson, N. C. Jacobus, and K. T. Soucy, J. Amer. Chem. Soc.,86, 4021 (1964).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1958–1961, September, 1968.

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Petrosyan, V.S., Rozenberg, V.N., Bundel', Y.G. et al. Proton magnetic resonance spectra of benzylmercury halides. Russ Chem Bull 17, 1867–1870 (1968). https://doi.org/10.1007/BF00904972

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Keywords

  • Methylene
  • Acetate
  • Chloride
  • Mercury
  • Bromide