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Synthesis of some 16,18-dimethyl-D-homosteroids

Conclusions

A series of 16,16-dimethyl derivatives of D-homoestrone and D-homotestosterone has been obtained from 1-vinyltetralin-1,6-diol (I), 1-vinyl-6-methoxytetral-1-ol (II), and 2,5,5-trimethylcyclohexane-1,3-dione (III).

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Literature cited

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2326–2332, October, 1968.

The mass spectra were taken and interpreted by V. I. Zaretskii and V. L. Sadovskaya for which the authors thank them.

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Al'Safar, N., Zakharychev, A.V., Ananchenko, S.N. et al. Synthesis of some 16,18-dimethyl-D-homosteroids. Russ Chem Bull 17, 2196–2200 (1968). https://doi.org/10.1007/BF00904046

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Keywords

  • Diol
  • Dione