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Fluorine-containing β-sultones

XXIX. β-alkoxy-β-sultones and β-alkoxy-β-pyrosultones

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Conclusions

  1. 1.

    The sulfotrioxidation of alkyl polyfluoroalkenyl ethers has been studied. The electron-donor ability of the latter is principally determined by theΠ-component of the multiple bond.

  2. 2.

    β-Alkoxy-β-sultones andβ-alkoxy-β-pyrosultones have been prepared and their ability to undergo anionotropic conversions has been demonstrated.

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Literature cited

  1. 1.

    E. E. Gilbert, Chem. Rev.,62, 549 (1962).

  2. 2.

    G. A. Sokol'skii and M. A. Dmitriev, ZhOKh,31, 1653, 2743 (1961).

  3. 3.

    M. A. Dmitriev, G. A. Sokol'skii, and I. L. Knunyants, Khim. Nauka i Prom.,3, 826 (1958); DAN SSSR,124, 581 (1959); Izv. AN SSSR, Otd. Khim. Nauk, 1960, 847.

  4. 4.

    G. A. Sokol'skii and I. L. Knunyants, Izv. AN SSSR, Ser. Khim.,1965, 1655.

  5. 5.

    I. L. Knunyants, G. A. Sokol'skii, and M. A. Dmitriev, Izd. AN SSSR, Ser. Khim.,1966, 1022.

  6. 6.

    G. A. Sokol'skii, M. A. Belaventsev, L. I. Ragulin, and I. L. Knunyants, Izd. AN SSSR, Ser. Khim.,1967, 2024.

  7. 7.

    G. A. Sokol'skii and I. L. Knunyants, Izv. AN SSSR, Otd. Khim. Nauk,1967, 1606.

  8. 8.

    L. I. Ragulin, P. P. Ropalo, G. A. Sokol'skii, and I. L. Knunyants, Izv. AN SSSR, Ser. Khim.,1967, 1754.

  9. 9.

    G. A. Sokol'skii, M. A. Belaventsev, and I. L. Knunyants, Izv. AN SSSR, Ser. Khim.,1967, 1524.

  10. 10.

    G. A. Sokol'skii, M. A. Dmitriev, and I. L. Knunyants, Izv. AN SSSR, Otd. Khim. Nauk,1960, 1231.

  11. 11.

    I. L. Knunyants, ZhVKhO, im. D. I. Mendeleeva,7, 276 (1962).

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2296–2303, October, 1968.

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Belaventsev, M.A., Sokol'skii, G.A. & Knuayants, I.L. Fluorine-containing β-sultones. Russ Chem Bull 17, 2170–2175 (1968). https://doi.org/10.1007/BF00904039

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Keywords

  • Ether
  • Multiple Bond