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Penta- and tetracoordinated phosphorous in reactions of biacetyl with diethylacetylphosphite and diethyl chlorophosphite

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Conclusions

Diethylacetyl phosphite and diethyl chlorophosphite react with biacetyl, intermediately forming, as do other derivatives of phosphorous acid, 1,3,2-dioxaphospholenes with a pentacoordinated phosphorous atom; the latter are rapidly transformed to noncyclic or cyclic derivatives of tetracoordinated phosphorous.

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2609–2611, November, 1968.

Deceased.

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Levin, Y.A., Gozman, I.P. & Salikhov, S.G. Penta- and tetracoordinated phosphorous in reactions of biacetyl with diethylacetylphosphite and diethyl chlorophosphite. Russ Chem Bull 17, 2466–2468 (1968). https://doi.org/10.1007/BF00903403

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Keywords

  • Diethyl
  • Phosphorous Acid
  • Penta
  • Phosphite
  • Biacetyl