Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

Spectral, fluorescent, photochemical and laser properties of some organic compound vapors

  • 56 Accesses

  • 33 Citations

Abstract

Absorption and fluorescence spectra of rarefied vapors ofp-terphenyl, 1,4-bis-[2(5-phenyloxazolyl)]-benzene, 2,5-diphenyl-1,3,4-oxadiazole, 2,5-diphenyl-1,3-oxazole, 2,5-diphenylfuran are measured. Extinction coefficients, quantum yields of fluorescence and one-photon decomposition of molecules are determined for vapors excited by pulsed laser radiation at 266 and 355 nm in the temperature range from 200 to 400°C. It is shown that for all cases studied the one-photon decomposition is only a small part of the total quantum yield of the radiationless deactivation of the fluorescent state. Laser action has, for the first time, been obtained in 2,5-diphenylfuran vapor at 356 nm.

This is a preview of subscription content, log in to check access.

References

  1. 1.

    N.A.Borisevitch, I.I.Kalosha, V.A.Tolkatchev: Zh. Prikl. Spektrosk.19, 1108–1109 (1973)

  2. 2.

    B.Steyer, F.P.Schäfer: Appl. Phys.7, 113–122 (1975)

  3. 3.

    P.W.Smith, P.F.Liao, C.V.Shank, C.Lin, P.J.Maloney: IEEE J. Quant. Electr. QE-11, 84 (1975)

  4. 4.

    Yu.Yu.Stoilov, K.K.Trusov: Kvantovaya Elektron.1, 1458–1460 (1974)

  5. 5.

    L.G.Pikulik, V.A.Yakovenko, A.D.Das'ko: Zh. Prikl. Spektrosk.23, 493 (1975)

  6. 6.

    G.Marowsky, R.Cordray, F.K.Tittel, W.L.Wilson: Appl. Phys. Lett.32, 561–563 (1978)

  7. 7.

    G.Marowsky, R.Cordray, F.K.Tittel, W.L.Wilson, C.B.Collins: Appl. Phys. Lett.33, 59–61 (1978)

  8. 8.

    N.A.Borisevitch, A.Ya.Gorelenko, I.I.Kalosha, V.A.Povedailo, V.A.Tolkachev: Zh. Prikl. Spektrosk28, 906–908 (1978)

  9. 9.

    V.S.Zuev, O.A.Logunov, Yu.V.Savinov, A.V.Startsev, Yu.Yu.Stoilov: Appl. Phys.17, 321–323 (1978)

  10. 10.

    N.A.Borisevitch, I.I.Kalosha, V.A.Tokatchev: Dokl. Akad. Nauk SSSR218, 74–76 (1974)

  11. 11.

    V.S.Zuev, Yu.Yu.Stoilov, K.K.Trusov: Zh. Prikl. Spektrosk.23, 1003–1008 (1975)

  12. 12.

    G.A.Abakumov, B.I.Polyakov, A.P.Simonov: Opt. Spektrosk.45, 887–890 (1978)

  13. 13.

    G.A.Abakumov, C.S.Bagdasarov et al.: Kvantovaya Elektron.4, 1152–1153 (1977)

  14. 14.

    G.A.Abakumov, S.A.Vorobjev, V.F.Pykelny, A.P.Simonov: Opt. Spektrosk.44, 486–488 (1978)

  15. 15.

    J.Kelly, F.O.Rice: J. Phys. Chem.68, 3794–3796 (1964)

  16. 16.

    I.B.Berlman:Handbook of Fluorescence Spectra of Aromatic Molecules, 2nd ed. (Academic Press, New York, London 1971) pp. 220, 285, 291, 299, 303

  17. 17.

    P.W.Smith, P.F.Liao, C.V.Shank, T.K.Gustafson, C.Lin, P.J.Maloney: Appl. Phys. Lett.25, 144–146 (1974)

  18. 18.

    T.Sakurai, A.Ogishima, M.Sugawara: Opt. Commun.25, 75–78 (1978)

  19. 19.

    G.A.Abakumov, Yu.M.Anisimov, B.I.Polyakov, A.P.Simonov: Kvantovaya Elektron.6, 397–400 (1979)

  20. 20.

    J.Weber: Phys. Lett. A.45, 35–36 (1973)

Download references

Author information

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Abakumov, G.A., Anisimov, Y.M., Polyakov, B.I. et al. Spectral, fluorescent, photochemical and laser properties of some organic compound vapors. Appl. Phys. 23, 83–87 (1980). https://doi.org/10.1007/BF00899574

Download citation

PACS

  • 33
  • 82.50
  • 42.55