Soviet Physics Journal

, Volume 27, Issue 9, pp 753–757 | Cite as

Fusion and crystallization of the compounds Cd4Sb3 and ZnSb

  • V. I. Psarev
  • I. V. Psareva
  • V. G. Kirii
Solid State Physics


Conditions are found which stabilize the crystalline structure and permit congruent fusion of the metastable compound Cd4Sb3. A melt corresponding to the composition of this compound has two structural states which manifest themselves under different crystallization conditions. Upon fusion of the compound ZnSb a melt is formed which has an unstable structural state, which changes significantly upon even slight superheating. Experimental results are explained from the viewpoint of new concepts of the formation and change of the liquid structural state.


Crystallization Crystalline Structure Structural State Crystallization Condition Metastable Compound 
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Copyright information

© Plenum Publishing Corporation 1985

Authors and Affiliations

  • V. I. Psarev
    • 1
  • I. V. Psareva
    • 1
  • V. G. Kirii
    • 1
  1. 1.I. N. Ul'yanov Chuvash State UniversityUSSR

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