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Determination of the rate constants of the reaction of pentaerythritol tetravalerate peroxy radicals with polyfunctional phosphites at high temperature

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Abstract

The effectiveness of a number of aromatic phosphites as inhibitors of the high-temperature autooxidation of pentaerythritol tetravalerate was studied, and the rate constants of the reaction of its peroxide radicals with aromatic phosphites at 200°C were determined

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Additional information

Institute of Chemistry, Bashkir Science Center, Urals Branch of the Russian Academy of Sciences, 450054 Ufa. Institute of Organic Chemistry, Academy of Sciences of the Uk-raine, 252000 Kiev. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 2, pp. 289–291, February, 1992.

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Gerchikov, A.Y., Kozhushko, B.N. & Vishnevskii, O.V. Determination of the rate constants of the reaction of pentaerythritol tetravalerate peroxy radicals with polyfunctional phosphites at high temperature. Russ Chem Bull 41, 215–217 (1992). https://doi.org/10.1007/BF00869503

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Keywords

  • aromatic phosphites
  • inhibition
  • pentaerythritol tetravalerate
  • autooxidation
  • rate constants