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Catalytic activity and selectivity of homogeneous and heterogeneous rhodium catalysts in hydrogenation and isomerization reactions

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Conclusions

  1. 1.

    A study was made of the activity and selectivity of action of some rhodium catalysts, representing heterogeneous and homogeneous complexes with N-phenylanthranilic acid and L-tyrosine.

  2. 2.

    The direction of hydrogen addition to a system of conjugated double bonds, the ratio in the rates of the reaction for the isomerization and hydrogenation of the C=C bond of the studied olefins, and also the selectivity of the process, are all independent of the phase condition of the catalyst.

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Literature cited

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 404–408, February, 1971.

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Freidlin, L.K., Litvin, E.F. & Topuridze, L.F. Catalytic activity and selectivity of homogeneous and heterogeneous rhodium catalysts in hydrogenation and isomerization reactions. Russ Chem Bull 20, 336–339 (1971). https://doi.org/10.1007/BF00869036

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Keywords

  • Hydrogenation
  • Catalytic Activity
  • Double Bond
  • Phase Condition
  • Rhodium