A π-crotyl derivative of Ti(III) is formed on interaction of (π-C2H5)2TiCl2 with EtMgBr.
The crotyl grouping is formed from two molecules of ethylene produced in the course of the reaction.
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Krashina, E.V., Borod'ko, Y.G., Plakhova, E.I. et al. Formation of a π-crotyl complex of Ti (III) in the reaction between (π-C5H5)2TiCl2 and EtMgBr. Russ Chem Bull 19, 887–888 (1970). https://doi.org/10.1007/BF00867261