Starting from lithium-p-carboranes, the C-iodo-, mercapto-, benzoyl-, methylmercury-, ni-troso-, and amino-derivatives of p-carborane were obtained, p-Carboranesulfinic acid was also produced.
Iodine atoms in C-iodo-p-carborane have a “positive” character.
The reactivity of lithium-p-carborane is analogous to that of lithium-m-carborane.
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Zakharkin, L.I., Kalinin, V.N. & Zhigareva, G.G. Syntheses based on lithium derivatives of p-carborane. Russ Chem Bull 19, 857–859 (1970). https://doi.org/10.1007/BF00867250
- Iodine Atom