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Analysis of the conformational equilibrium of tris(chloromethyl)phosphine oxide

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  1. 1.

    The IR spectra, dipole moments, and Kerr constants of tris(chloromethyl)phosphine oxide (TCPO) were studied.

  2. 2.

    The equilibrium of two conformers is characteristic for TCPO in solution.

  3. 3.

    The forms participating in the equilibrium were identified, and concepts regarding the factors which stabilize them were expressed.

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Literature cited

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    O. A. Raevskii, F. G. Khalitov, and T. A. Zyablikova, Izv. Akad. Nauk SSSR, Ser. Khim., 348 (1972).

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    O. A. Raevskii, A. N. Vereshchagin, and F. G. Khalitov, Izv. Akad. Nauk SSSR, Ser. Khim., 353 (1972).

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    A. N. Vereshchagin, O. N. Nuretdinova, L. Z. Nikonova, and B. A. Arbuzov, Izv. Akad. Nauk SSSR, Ser. Khim., 758 (1971).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 710–712, March, 1972.

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Raevskii, O.A., Vereshchagin, A.N., Khalitov, F.G. et al. Analysis of the conformational equilibrium of tris(chloromethyl)phosphine oxide. Russ Chem Bull 21, 680–682 (1972).

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  • Oxide
  • Dipole Moment
  • Phosphine
  • Chloromethyl
  • Phosphine Oxide