The mechanism of the reaction of triphenylmethane derivatives with dialkylmercury compounds and triethylsilane was studied by the method of chemically induced dynamic nuclear polarization.
The so-called intermolecular hydride transfer reaction may proceed through a step involving one-electron transfer.
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I. P. Beletskaya, V. B. Vol'eva, S. V. Rykov, A. L. Buchachenko, and A. V. Kessenikh, Izv. Akad. Nauk SSSR, Ser. Khim., 545 (1971).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 684–687, March, 1972.
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Beletskaya, N.P., Rykov, S.V., Vol'eva, V.B. et al. Study of the mechanism of hydride transfer with the participation of triphenylmethane derivatives by the method of chemically induced dynamic nuclear polarization. Russ Chem Bull 21, 653–655 (1972). https://doi.org/10.1007/BF00863242
- Transfer Reaction
- Dynamic Nuclear Polarization
- Nuclear Polarization