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Study of the mechanism of hydride transfer with the participation of triphenylmethane derivatives by the method of chemically induced dynamic nuclear polarization

Conclusions

  1. 1.

    The mechanism of the reaction of triphenylmethane derivatives with dialkylmercury compounds and triethylsilane was studied by the method of chemically induced dynamic nuclear polarization.

  2. 2.

    The so-called intermolecular hydride transfer reaction may proceed through a step involving one-electron transfer.

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Literature cited

  1. 1.

    I. P. Beletskaya, V. B. Vol'eva, S. V. Rykov, A. L. Buchachenko, and A. V. Kessenikh, Izv. Akad. Nauk SSSR, Ser. Khim., 545 (1971).

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    O. A. Reutov, E. V. Uglova, and V. D. Makhaev, Dokl. Akad. Nauk SSSR,188, 833 (1969).

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    O. A. Reutov, E. V. Uglova, V. D. Makhaev, and V. S. Petrosyan, Zh. Organ. Khim.,6, 2153 (1970).

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    E. V. Uglova, V. D. Makhaev, and O. A. Reutov, Zh. Organ. Khim.,6, 1337 (1970).

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    R. S. Konar, Internal. J. Chem. Kinetics,2, 419 (1970).

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    L. H. Sommer and D. L. Bauman, J. Amer. Chem. Soc.,91, 7076 (1969).

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 684–687, March, 1972.

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Beletskaya, N.P., Rykov, S.V., Vol'eva, V.B. et al. Study of the mechanism of hydride transfer with the participation of triphenylmethane derivatives by the method of chemically induced dynamic nuclear polarization. Russ Chem Bull 21, 653–655 (1972). https://doi.org/10.1007/BF00863242

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Keywords

  • Hydride
  • Transfer Reaction
  • Dynamic Nuclear Polarization
  • Nuclear Polarization
  • Triphenylmethane