Microcalorimetric measurements were carried out on the heat effects of ion exchange in a system containing natural heulandite and aqueous solutions of pairs of electrolytes at 303.15 K. The electrolytes studied were NaCl, KCl, RbCl, CsCl, and NH 4 Cl. The ion exchange enthalpy decreases in the cation series: Na+ > NH4 + > K+ > Rb+ > Cs+.
This is a preview of subscription content, log in to check access.
Buy single article
Instant access to the full article PDF.
Price includes VAT for USA
Subscribe to journal
Immediate online access to all issues from 2019. Subscription will auto renew annually.
This is the net price. Taxes to be calculated in checkout.
G. N. Al'tshuler and G. Yu. Shkurenko,Izv. Akad. Nauk, Ser. Khim., No. 7, 1474 (1990).
G. N. Al'tshuler and G. Yu. Shkurenko,Izv. Sib. Otd. Akad. Nauk, Ser. Khim. Nauk, No. 5, Issue 2, 121 (1985).
G. V. Tsitsishvili, T. G. Andronikashvili, G. N. Kirov, and L. D. Filizova,Natural Zeolites [in Russian], Khimiya, Moscow (1985).
D. N. Breck,Zeolite Molecular Sieves: Structure, Chemistry, and Use, Wiley-Interscience, New York (1974).
Institute of the Chemistry of Carbon Materials, Siberian Branch, Russian Academy of Sciences, 650099 Kemerovo. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 3, pp. 754–756, March, 1992.
About this article
Cite this article
Al'tshuler, G.N., Shkurenko, G.Y. Thermodynamics of cation exchange on natural heulandite. Russ Chem Bull 41, 592–593 (1992). https://doi.org/10.1007/BF00863095
- cation exchange
- alkali metals
- natural heulandite