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Anomalous relationship of the energy of the sequential ionization of molecular systems as a result of effective electron-electron attraction in molecules

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Abstract

Conditions were found, under which an anomalous relationship should be observed in the energies of sequential ionization of molecules ("anomalous" molecules) such that a subsequent potential (In+1) is less than the preceding potential (In). These conditions are a function of the electronic vibrational instability of molecules or their ions upon change in the number of electrons in the system. An interrelationship was found with the previously proposed concept of effective electron—electron attraction in molecular systems.

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Literature cited

  1. 1.

    E. H. Lieb,Intern. J. Quantum Chem.,24, No. 1, 243 (1983).

  2. 2.

    S. P. Ionov, G. V. Ionova, V. S. Lyubimov, and A. Yu. Aleksandrov,Pis'ma Zh. Éksp. Teor. Fiz.,12, No. 8, 544 (1970).

  3. 3.

    E. F. Makarov, I. I. Amelin, and S. P. Ionov,Phys. Status Solidi (b),71, No. 1, 135 (1975).

  4. 4.

    S. P. Ionov, V. S. Lyubimov (Lubimov), E. F. Makarov, G. V. Ionova, and G. V. Uimin,Phys. Status Solidi (b),72, No. 3, 515 (1975).

  5. 5.

    S. P. Ionov,Izv. Akad. Nauk, Ser. Fiz.,49, No. 2, 310 (1985).

  6. 6.

    S. P. Ionov, V. A. Kondrat'ev, and V. S. Lyubimov,Dokl. Akad. Nauk,277, No. 2, 399 (1984).

  7. 7.

    S. P. Ionov, G. V. Ionova, A. T. Mailybaev, L. A. Manakova, and G. K. Semin,Izv. Akad. Nauk, Ser. Fiz.,45, No. 3, 589 (1981).

  8. 8.

    I. B. Bersuker and V. Z. Polinger,Vibronic Interactions in Molecules and Crystals [in Russian], Nauka, Moscow (1983), p. 333.

  9. 9.

    S. P. Ionov, V. S. Lyubimov, and M. A. Porai-Koshits,Izv. Akad. Nauk, Ser. Khim., No. 12, 2692 (1969).

  10. 10.

    R. H. Voegeli, H. C. Kang, R. G. Finke, and V. Boekelheide,J. Am. Chem. Soc.,108, No. 11, 7010 (1986).

  11. 11.

    V. S. Lyubimov, Doctoral Dissertation, Physical and Mathematical Sciences, Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow (1989), p. 150.

  12. 12.

    K. Prassides and P. N. Schatz,Chem. Phys. Lett.,178, Nos. 2–3, 227 (1991).

  13. 13.

    P. W. Anderson,Phys. Rev. Lett.,35, No. 8, 963 (1975).

  14. 14.

    H. Fritzsche,Physics Today, No. 1, 34 (1984).

  15. 15.

    S. P. Ionov,Dokl. Akad. Nauk,316, No. 6, 1383 (1991).

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Additional information

Institute of Physiologically Active Compounds, Russian Academy of Sciences, 142432 Chernogolovka. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 3, pp. 738–741, March, 1992.

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Ionov, S.P., Lyubimov, V.S. Anomalous relationship of the energy of the sequential ionization of molecular systems as a result of effective electron-electron attraction in molecules. Russ Chem Bull 41, 579–581 (1992). https://doi.org/10.1007/BF00863089

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Keywords

  • ionization potential
  • electronic-vibrational interaction
  • valence disproportionation reaction
  • mixed-valence compounds