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Stereochemistry and reactivity of unsaturated compounds

Communication 11. Synthesis of pure stereoisomers of 1-substituted functional derivatives of the Δ4-octalin series

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Conclusions

  1. 1.

    We synthesized the pure cis-trans isomers of Δ4-octalin-1-carboxylic acid, its methyl ester, 1-hydroxymethyl-Δ4-octalin, and Δ4-1-octalinaldehyde, and also the methyl ester of cis-Δ4-1-octalylacetic acid and cis-1-(2-hydroxyethyl)-Δ4-octalin.

  2. 2.

    A study was made of the epimerization of Δ4-1-octalinaldehyde.

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Literature cited

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Deceased.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1752–1757, August, 1971.

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Andreev, V.M., Kugatova-Shemyakina, G.P. & Smirnova, G.P. Stereochemistry and reactivity of unsaturated compounds. Russ Chem Bull 20, 1645–1649 (1971). https://doi.org/10.1007/BF00860020

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Keywords

  • Methyl
  • Ester
  • Methyl Ester
  • Unsaturated Compound