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Pyrolysis of methylphenyldichlorosilane

Conclusions

  1. 1.

    The pyrolysis of methylphenyldichlorosilane was studied.

  2. 2.

    A radical mechanism was proposed for the pyrolysis of methylphenyldichlorosilane.

  3. 3.

    Compounds containing two silicon atoms, connected with each other through methylene and phenylene bridges, are formed during the pyrolysis of methylphenyldichlorosilane.

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Literature cited

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    G. Fritz, Z. Naturforsch.,12b, 66 (1957); Z. Anorg. Allgem. Chem.,302, 60 (1959); Angew. Chem.,79, 657 (1967); G. Fritz and D. Ksinsik, Z. Anorg. Allgem. Chem.,322, 46 (1963).

  2. 2.

    K. A. Andrianov and V. M. Kotov, Dokl. Akad. Nauk SSSR,167, 811 (1966).

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    K. A. Andrianov and V. M. Kotov, Izv. Akad. Nauk SSSR, Ser. Khim.,1265 (1969).

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    N. N. Sokolov, K. A. Andrianov, and S. M. Anisimova, Zh. Obshch. Khim.,25, 675 (1955).

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    G. Fritz, H. J. Buhl, and D. Kummer, Z. Anorg. Allgem. Chem.,327, 165 (1964).

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    N. Bilow, J. L. Brady, and C. L. Segal, J. Org. Chem.,26, 929 (1961).

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 359–365, February, 1972.

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Andrianov, K.A., Kotov, V.M. & Kovalenko, V.Y. Pyrolysis of methylphenyldichlorosilane. Russ Chem Bull 21, 310–315 (1972). https://doi.org/10.1007/BF00857791

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Keywords

  • Methylene
  • Silicon
  • Phenylene
  • Pyrolysis
  • Silicon Atom