Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

Pyrolysis of methylphenyldichlorosilane


  1. 1.

    The pyrolysis of methylphenyldichlorosilane was studied.

  2. 2.

    A radical mechanism was proposed for the pyrolysis of methylphenyldichlorosilane.

  3. 3.

    Compounds containing two silicon atoms, connected with each other through methylene and phenylene bridges, are formed during the pyrolysis of methylphenyldichlorosilane.

This is a preview of subscription content, log in to check access.

Literature cited

  1. 1.

    G. Fritz, Z. Naturforsch.,12b, 66 (1957); Z. Anorg. Allgem. Chem.,302, 60 (1959); Angew. Chem.,79, 657 (1967); G. Fritz and D. Ksinsik, Z. Anorg. Allgem. Chem.,322, 46 (1963).

  2. 2.

    K. A. Andrianov and V. M. Kotov, Dokl. Akad. Nauk SSSR,167, 811 (1966).

  3. 3.

    K. A. Andrianov and V. M. Kotov, Izv. Akad. Nauk SSSR, Ser. Khim.,1265 (1969).

  4. 4.

    N. N. Sokolov, K. A. Andrianov, and S. M. Anisimova, Zh. Obshch. Khim.,25, 675 (1955).

  5. 5.

    G. Fritz, H. J. Buhl, and D. Kummer, Z. Anorg. Allgem. Chem.,327, 165 (1964).

  6. 6.

    N. Bilow, J. L. Brady, and C. L. Segal, J. Org. Chem.,26, 929 (1961).

Download references

Author information

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 359–365, February, 1972.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Andrianov, K.A., Kotov, V.M. & Kovalenko, V.Y. Pyrolysis of methylphenyldichlorosilane. Russ Chem Bull 21, 310–315 (1972).

Download citation


  • Methylene
  • Silicon
  • Phenylene
  • Pyrolysis
  • Silicon Atom