The degree of displacement of chemical equilibrium in dissociation reactions, including three-particle recombination due to laser radiation at an isolated vibrational degree of freedom of the molecules, is determined. Dependences of the “vibrational temperature” and the chemical equilibrium constant on the vibrational excitation probability are obtained.
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Translated from Zhurnal Prikladnoi Mekhaniki i Tekhnicheskoi Fiziki, No. 1, pp. 10–12, January–February, 1976.
The authors wish to express their appreciation to R. V. Khokhlov for support and interest in the work.
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Gordiets, B.F., Osipov, A.I. & Panchenko, V.Y. Shift of chemical equilibrium in a resonance infrared radiation field. J Appl Mech Tech Phys 17, 6–8 (1976). https://doi.org/10.1007/BF00857740
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