The formation of 3-nitroisoxazoline N-oxide in the reaction of diazomethane with trinitromethane goes through the intermediate step of the O-methyl ester of trinitromethane.
The O-chloromethyl ester of trinitromethane is formed when chlorotrinitromethane is reacted with an equimolar amount of diazomethane.
The O-methyl ester of trinitromethane is formed when the bromo- and iodotrinitromethanes are reacted with a double amount of diazomethane.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1560–1562, July, 1971.
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Onishchenko, A.A., Chlenov, I.E., Makarenkova, L.M. et al. Reaction of trinitromethane and its halo derivatives with diazomethane. Russ Chem Bull 20, 1460–1462 (1971). https://doi.org/10.1007/BF00857417
- Equimolar Amount
- Intermediate Step