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Radical addition of halogen-containing addends to unsaturated compounds containing electron-acceptor groups

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Conclusions

The radical addition of CHCl3 to trichloroalkenes with the structure CCl3(CH2)nCH=CH2; n=0,1,2,4; that of bromotrichloromethane to 5,5,5-trichloro-1-pentene, allyl and vinyl esters of trichloroacetic acid; and the addition of hydrogen bromide to 4,4,4-trichloro-1-butene and 5,5,5-trichloro-1-pentene were studied.

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Deceased.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1468–1472, July, 1971.

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Khorlina, M.Y., Vasil'eva, T.T., Shvarts, I.A. et al. Radical addition of halogen-containing addends to unsaturated compounds containing electron-acceptor groups. Russ Chem Bull 20, 1370–1373 (1971). https://doi.org/10.1007/BF00857392

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Keywords

  • Hydrogen
  • Ester
  • Bromide
  • CHCl3
  • Vinyl