Some mono- and di-vinylacetylenic derivatives of aromatic hydrocarbons were obtained by the successive treatment of unsaturated aromatic ketones with phosphorus pentachloride and sodium amide.
The introduction of a phenyl substituent into the vinyl group sharply raises the stability of these compounds.
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I. L. Kotlyarevskii, M. I. Bardamova, and T. G. Shishmakova, Izv. AN SSSR, Ser. khim.,1966, No. 5.
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Shishmakova, T.G., Bardamova, M.I. & Kotlyarevskii, I.L. Synthesis of vinylacetylenic aromatic hydrocarbons from unsaturated ketones. Russ Chem Bull 15, 335–336 (1966). https://doi.org/10.1007/BF00856073