The spectropolarimetric method was used to investigate the structure of polymers produced on the basis of (−)-menthylmethacrylate under conditions of radical and anionic polymerization.
The applicability of the one-membered Drude equation within the interval 302–607 mμ was demonstrated, and the constants of the equations (A and λ0) were determined.
The independence of λ0 from the solvent and method of production of the polymers was demonstrated. The value of A increases in the series of polymers: radical, thermal, anionic. The negative values of the peaks increase in the same order.
The value of A varies depending on the stereoregularity of the polymer. The increase in A is related to an increse in the degree of crystallinity (x-ray diffraction study) and stereoregularity (IR spectra).
This is a preview of subscription content, log in to check access.
Buy single article
Instant access to the full article PDF.
Price includes VAT for USA
Subscribe to journal
Immediate online access to all issues from 2019. Subscription will auto renew annually.
This is the net price. Taxes to be calculated in checkout.
C. L. Arkus and D. W. West, J. Chem. Soc.,1959, 2699.
G. J. Schmitt and C. Schuerch, J. Polymer Sci.,49, 287 (1961).
G. Natta, M. Farina, M. Peraldo, and G. Bressan, Makromol. Chem.,43, 68 (1961).
R. C. Schulz and H. Hilpert, Makromol. Chem.,55, 132 (1962);81, 273 (1965).
E. I. Klabunovskii, Yu. I. Petrov, and M. I. Shvartsman, Vysokomolekul. Soedineniya,6, 1487, 1579, 1806 (1964).
P. Pino, F. Giardelli, G. P. Lorenzi, and G. Montagnoli, Makromol. Chem.,61, 207 (1963); Vysokomolekul. soedineniya,3, 1547 (1961).
M. Goodman, K. J. Clark, M. A. Stake, and A. Abe, Makromol. Chem.,72, 131 (1964).
Y. Minoura and N. Sakota, J. Chem. Soc. Japan. (PCS)83, 912 (1962).
W. J. Heller, J. Phys. Chem.,62, 1569 (1958).
H. Sobue, K. Matsuzaki, S. Nakano, J. Polymer Sci.,A2, 3339 (1964); Report at the International Symposium on the Chemistry of High-Molecular Compounds, Prague (1965), p. 109.
The authors would like to thank O. N. Andrianova for kindly providing the possibility of working on the spectropolarimeter.
About this article
Cite this article
Klabunovskii, E.I., Shvartsman, M.I. & Petrov, Y.I. Investigation of the structure of poly-(−)-menthylmethacrylates by a spectropolarimetric method. Russ Chem Bull 15, 205–209 (1966). https://doi.org/10.1007/BF00856039
- Diffraction Study
- Peak Increase
- Anionic Polymerization
- Drude Equation