Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

IR and mass spectrometric investigation of phenyltrichloromethylmercury

  • 16 Accesses

Conclusions

  1. 1.

    The IR spectra of C6H5HgCCl3, (C6H5)2Hg and C6H5HgCl, were studied, and a partial assignment of the frequencies to the normal vibrations of the phenyltrichloromethylmercury molecule was performed.

  2. 2.

    The characteristic frequencies in the IR spectrum and the peaks in the mass spectra were discovered, permitting the identification of C6H5HgCCl3 and possible impurities-(C6H5)2Hg and C6H5HgCl.

This is a preview of subscription content, log in to check access.

Literature cited

  1. 1.

    D. Seyferth, J. M. Burlitch, R. J. Minasz, J. Y.-P. Mui, H. D. Simmons, Jr., A. J. H. Treiber, and S. R. Dowd, J. Amer. Chem. Soc.,87, 4259 (1965).

  2. 2.

    O. A. Reutov and A. N. Lovtsova, Dokl. Akad. Nauk SSSR,139, 622 (1961).

  3. 3.

    E. E. Schweizer and G. J. O'Neil, J. Organ. Chem.,28, 851 (1963).

  4. 4.

    T. J. Logan, J. Organ. Chem.,28, 1129 (1963).

  5. 5.

    G. A. Razuvaev, V. I. Shcherbakov, and S. F. Zhil'tsov, Izv. Akad. Nauk SSSR, Ser. Khim., 2803 (1968).

  6. 6.

    D. Seyferth and J. M. Burlitch, J. Organometal. Chem.,4, 127 (1965).

  7. 7.

    J. H. S. Green, Spectrochim. Acta24A, 863 (1968).

  8. 8.

    Ya. Mink, Dissertation [in Russian], Moscow (1968).

  9. 9.

    D. H. Whiffen, J. Chem. Soc., 1350 (1956).

  10. 10.

    C. V. Stephenson, W. C. Coburn, Jr., and W. S. Wilcox, Spectrochim. Acta,17, 933 (1961).

  11. 11.

    C. V. Stephenson and W. C. Coburn, Jr., J. Chem. Phys.,42, 35 (1965).

  12. 12.

    G. Hertzberg, Vibrational and Rotational Spectra of Polyatomic Molecules [Russian translation], IL (1949), p. 391.

  13. 13.

    E. Spinner, J. Chem. Soc., 4217 (1964).

  14. 14.

    L. Andrews, J. Chem. Phys.,48, 979 (1968).

  15. 15.

    D. E. Milligan and M. E. Jacox, J. Chem. Phys.,47, 703 (1967).

  16. 16.

    Ya. Mink, Yu. A. Pentin, and I. P. Beletskaya, Zh. Organ. Khimii,4, 195 (1968).

  17. 17.

    G. E. Coates and D. Ridley, J. Chem. Soc., 166 (1964).

  18. 18.

    T. J. Logan, Org. Synth.,56, 98 (1966).

Download references

Author information

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1179–1185, June, 1971.

In conclusion, we should like to express our gratitude to I. P. Yakovlev for his useful discussion, V. T. Aleksanyan, L. I. Komarova, O.S. Chizhov, and B. M. Zolotarev for taking a number of the spectra.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Mal'tsev, A.K., Mikaélyan, R.G. & Nefedov, O.M. IR and mass spectrometric investigation of phenyltrichloromethylmercury. Russ Chem Bull 20, 1093–1097 (1971). https://doi.org/10.1007/BF00855358

Download citation

Keywords

  • Mass Spectrum
  • Characteristic Frequency
  • Normal Vibration
  • Partial Assignment
  • Spectrometric Investigation