The direction of the group dipole moments of p-tolylsilane was established from the change in the internal chemical shift of the protons of the CH3 and SiH3 groups.
The contribution of the reaction field of the solvent primarily determines the change in the chemical shifts of the silyl group of p-tolylsilane in nonaromatic solvents.
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Andrianov, K.A., ReikhsfeL'd, V.O. & Evdokimov, A.M. Effect of reaction field on chemical shift of protons of p-tolylsilane. Russ Chem Bull 21, 2303–2305 (1972). https://doi.org/10.1007/BF00855331
- Chemical Shift
- Dipole Moment
- Reaction Field
- Internal Chemical