Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

Effect of reaction field on chemical shift of protons of p-tolylsilane

  • 21 Accesses


  1. 1.

    The direction of the group dipole moments of p-tolylsilane was established from the change in the internal chemical shift of the protons of the CH3 and SiH3 groups.

  2. 2.

    The contribution of the reaction field of the solvent primarily determines the change in the chemical shifts of the silyl group of p-tolylsilane in nonaromatic solvents.

This is a preview of subscription content, log in to check access.

Literature cited

  1. 1.

    I. E. Saratov and V. O. Reikhsfel'd, Zh. Obshch. Khim.,37, 651 (1967).

  2. 2.

    J. W. Emsley, J. Feeney, and L. H. Sutcliffe, High Resolution Nuclear Magnetic Resonance Spectroscopy [Russian translation], Mir (1968).

  3. 3.

    P. Laszlo, Progr. NMR Spectr.,3, 231 (1967).

  4. 4.

    B. I. Ionin and B. A. Ershov, Nuclear Magnetic Resonance Spectroscopy in Organic Chemistry [in Russian], Khimiya (1967).

  5. 5.

    L. Onsager, J. Am. Chem. Soc.,58, 1486 (1936).

  6. 6.

    P. Dichl and R. Freeman, Mol. Phys.,4, 39 (1961).

  7. 7.

    A. I. Kitaigorodskii, Organic Crystal Chemistry [in Russian] (1955).

  8. 8.

    G. Ross and R. A. Sack, Proc. Phys. Soc.,B63, 893 (1950).

  9. 9.

    V. O. Reikhsfel'd, Zh. Organ. Khim.,31, 1576 (1961).

  10. 10.

    L. Fieser, Modern Experimental Methods in Organic Chemistry [Russian translation], Mir (1960).

Download references

Author information

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2358–2360, October, 1972.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Andrianov, K.A., ReikhsfeL'd, V.O. & Evdokimov, A.M. Effect of reaction field on chemical shift of protons of p-tolylsilane. Russ Chem Bull 21, 2303–2305 (1972). https://doi.org/10.1007/BF00855331

Download citation


  • Chemical Shift
  • Dipole Moment
  • Silyl
  • Reaction Field
  • Internal Chemical